Journal of Jianghan University (Natural Science Edition) ›› 2021, Vol. 49 ›› Issue (6): 20-28.doi: 10.16389/j.cnki.cn42-1737/n.2021.06.002

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Research Progress of High-Safety Flame-Retardant Polymer Electrolytes for Lithium-Ion Batteries

CHEN Jia,LIU Xueqing,LIU Zhihong,LIU Jiyan   

  1. Key Laboratory of Optoelectronic Chemical Materials and Devices,Ministry of Education,School of Chemical and Environmental Engineering,Jianghan University,Wuhan 430056,Hubei,China
  • Published:2021-12-17

Abstract: Flammable polymer electrolytes are prone to fire after the abuse of short circuits,mechanical shock,and thermal runaway. Therefore,flame-retardant modification for lithiumion batteries polymer electrolytes exhibits particularly necessary. This paper reviews the research progress of flame-retardant polymer electrolytes. First,the two flame-retardant mechanisms of gas-phase and condensed phase during the combustion of polymer electrolytes,as well as various evaluation indicators for flame-retardant performance,are introduced. Then it summarizes the advantages and disadvantages of different flame-retardant compounds, and the flame retardants of polymer electrolytes have been classified for discussion according to the differences in flame-retardant elements. Finally,the application prospects for polyphosphonate and phosphazene compounds in the field of flame-retardant polymer electrolytes are predicted,and the future research directions of flame-retardant polymer electrolytes are prospected.

Key words: lithium-ion battery, safety, polymer electrolytes, flame-retardant

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