铁钛双金属MOF类芬顿材料的制备及其对卤代苯醌的吸附降解研究

doi:10.16389/j.cnki.cn42-1737/n.2022.02.004

江汉大学学报（自然科学版） ›› 2022, Vol. 50 ›› Issue (2): 32-38.doi: 10.16389/j.cnki.cn42-1737/n.2022.02.004

铁钛双金属MOF类芬顿材料的制备及其对卤代苯醌的吸附降解研究

刘帅，胡思前，朱天容^*

江汉大学光电化学材料与器件教育部重点实验室，湖北武汉 430056

发布日期:2022-03-28
通讯作者: 朱天容
作者简介:刘帅（1999— ），男，硕士生，研究方向：材料制备和应用。
基金资助:
2021 年江汉大学校级科研项目（2021yb030）

Preparation of Iron-titanium Bimetallic MOF Fenton Material and Study on Its Degradation of Halogenated Benzoquinones

LIU Shuai，HU Siqian，ZHU Tianrong^*

Key Laboratory of Optoelectronic Chemical Materials and Devices，Ministry of Education，Jianghan University，Wuhan 430056，Hubei，China

Published:2022-03-28
Contact: ZHU Tianrong

摘要/Abstract

摘要： 为了研究铁基双金属MOF材料降解水中卤代苯醌的应用可能性，采用溶剂热法以钛酸异丙酯、乙酰丙酮铁和2-氨基对苯二甲酸为原材料成功合成了铁钛双金属MOF材料，并对材料的结构和热学性能进行了表征，探讨了该材料对2，6-二氯-1，4-苯醌的吸附降解率。结果表明：当DCBQ初始浓度为1. 8 mg/L，投加30 mg Fe-Ti（0. 6∶2. 0）双金属MOF 材料和1 mL 3％的双氧水时，最佳降解率达到98. 58%。结果说明铁钛双金属MOF材料对降解饮用水中的卤代苯醌有较好的效果，使用双氧水效果更佳。

关键词: 双金属MOFs, 溶剂热法, 类芬顿法, 卤代苯醌

Abstract: To study the application possibility of iron-based bimetallic MOF material for the degradation of halogenated benzoquinones in water，we successfully synthesized irontitanium bimetallic MOF material using a solvothermal method with isopropyl titanate，iron acetylacetonate，and 2-aminoterephthalic acid as raw materials. We characterized its structure and thermal properties，and disussed its removal rate of 2，6-dichloro-1，4-benzoquinone. The results showed that when the initial concentration of DCBQ was 1. 8 mg/L，the amount of （Fe∶Ti = 0. 6∶2. 0） bimetallic MOF material was 30 mg，and the amount of 3% hydrogen peroxide was 1 mL， the optimal degradation rate was 98. 58%. The results demonstrate that iron-titanium bimetallic MOF has a good effect on the degradation of halogenated benzoquinones in drinking water，and the effect of hydrogen peroxide is better.

Key words: bimetal MOFs, solvothermal method, Fenton-like, halogenated benzoquinones

中图分类号:

刘帅，胡思前，朱天容. 铁钛双金属MOF类芬顿材料的制备及其对卤代苯醌的吸附降解研究[J]. 江汉大学学报（自然科学版）, 2022, 50(2): 32-38.

LIU Shuai，HU Siqian，ZHU Tianrong. Preparation of Iron-titanium Bimetallic MOF Fenton Material and Study on Its Degradation of Halogenated Benzoquinones[J]. Journal of Jianghan University (Natural Science Edition), 2022, 50(2): 32-38.

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铁钛双金属MOF类芬顿材料的制备及其对卤代苯醌的吸附降解研究

Preparation of Iron-titanium Bimetallic MOF Fenton Material and Study on Its Degradation of Halogenated Benzoquinones

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