江汉大学学报(自然科学版) ›› 2019, Vol. 47 ›› Issue (4): 345-350.doi: 10.16389/j.cnki.cn42-1737/n.2019.04.009

• 化学 • 上一篇    下一篇

武汉郊区农村民用生物质燃烧PM2.5排放特征

徐婷a,李嘉龙a,陈娜娜b,程晋俊a,叶巡a,张晖a,刘琼玉*a   

  1. 江汉大学 a. 工业烟尘污染控制湖北省重点实验室(江汉大学);b. 化学与环境工程学院,湖北 武汉 430056
  • 出版日期:2019-08-28 发布日期:2019-07-10
  • 通讯作者: 刘琼玉
  • 作者简介:徐婷(1996—),女,研究方向:污染控制化学。
  • 基金资助:
    国家自然科学基金资助项目(21806057);武汉研究院开放性课题资助项目(IWHS2016332)

Emission Characteristics of PM2.5 from Domestic Biomass in Rural Areas of Wuhan

XU Tinga,LI Jialonga,CHEN Nanab,CHENG Jinjuna,YE Xuna,ZHANG Huia,LIU Qiongyu*a   

  1. a. Hubei Key Laboratory of Industrial Fume and Dust Pollution Control(Jianghan University);b. School of Chemical and Environmental Engineering,Jianghan University,Wuhan 430056,Hubei,China
  • Online:2019-08-28 Published:2019-07-10
  • Contact: LIU Qiongyu

摘要: 选取武汉市木兰乡的木柴、竹子、油料作物秸秆(大豆秸秆和花生秸秆)4种当地典型民用生物质进行炉内燃烧实验,对燃烧排放的细颗粒物(PM2.5)进行采集和分析。结果表明,不同生物质的PM2.5排放因子相差较大,油料作物秸秆的PM2.5排放因子明显高于竹子和木柴,并且木柴的PM2.5排放因子随含水率增加而增大。碳组分是4 种生物质燃烧烟气PM2.5的主要成分,TC 占PM2.5 的55. 55% ~ 87. 91%。油料作物秸秆的TC 排放因子最高达5. 61 g/kg,为木柴的12. 5 倍。油料作物秸秆有机碳/元素碳(OC/EC)比值最高达10. 69,远远高于木柴燃烧烟气PM2.5的OC/EC 比值(1. 88),表明油料作物秸秆燃烧对二次气溶胶形成具有重要影响。4种生物质燃烧烟气PM2.5中重金属元素Cr、Mn、Ni、As、Cd、Pb 的排放因子有较大差异,其中油料作物秸秆的重金属排放因子均明显高于木柴。研究表明,当地普遍使用的木柴的燃烧烟气PM2.5及其碳组分和重金属的排放因子远低于其他3 种生物质,且干木柴的排放因子明显低于湿木柴。因此,建议当地村民使用风干状态下的木柴进行炊事活动,对油料作物秸秆利用其他方式处理,以减少对大气环境的不良影响。

关键词: 民用生物质, 细颗粒物, 碳组分, 重金属, 排放因子

Abstract: The four kinds of domestic biomass,including firewood,bamboo,oil crop straw(soybean straw and peanut straw) from rural areas of Wuhan were selected for combustion experiment in a furnace,and we collected and analyzed the fine particulate matter(PM2.5)emitted from the combustion. The results showed that emission factors of PM2.5 were influenced obviously by biomass fuel types. The emission factor of PM2.5 in oil crop straws was significantly higher than that of bamboo and firewood,and the PM2.5 emission factor of firewood increased with the increase of water content. Carbonaceous components were the most common components of PM2.5 in four kinds of biomass,which TC accounts for 55. 55% ~ 87. 91% of PM2.5. The TC emission factor of oil crop straw was up to 5. 61 g/kg,and which was 12. 5 times that of firewood. The OC/EC ratio of oil crop straw was up to 10. 69,which was much higher than that of firewood(1. 88),indicating that the combustion of oil crop straw had an essential effect on the formation of the secondary aerosol. The heavy metals emission factors of Cr,Mn,Ni,As,Cd and Pb in four biomass were significant different,and the heavy metal emission factors of oil crop straws were significantly higher than that of firewood. The results showed that the emission factors of PM2.5,carbonaceous components and heavy metals in the commonly used firewood were much lower than those of the other three kinds of biomass,and the emission factors of dry firewood were more depressed than those of wet firewood. Therefore,we suggested that the local villagers should use the air-dried firewood for cooking and treat the oil crop straw in other ways,so as to reduce the adverse effects on the atmospheric environment.

Key words: domestic biomass, fine particles, carbonaceous components, heavy metals, emission factors

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