江汉大学学报(自然科学版) ›› 2017, Vol. 45 ›› Issue (5): 411-417.doi: 10.16389/j.cnki.cn42-1737/n.2017.05.005

• 化学与化工 • 上一篇    下一篇

柚子皮生物吸附剂的制备及其对重金属铅离子的吸附应用

郭艳华,刘延湘,刘立,吴旺喜,张远方   

  1. 江汉大学 化学与环境工程学院,湖北 武汉 430056
  • 出版日期:2017-10-28 发布日期:2017-10-31
  • 作者简介:郭艳华(1960—),女,教授,研究方向:天然废弃物材料及功能材料在处理环境污染中的应用。
  • 基金资助:
    国家自然科学基金资助项目(21477091)

Preparation of Pomelo Peel Based Biosorbent and Its Adsorption Behavior for Heavy Metal Lead Ions

GUO Yanhua,LIU Yanxiang,LIU Li,WU Wangxi,ZHANG Yuanfang   

  1. School of Chemistry and Enviornmental Engineering,Jianghan University,Wuhan 430056,Hubei,China
  • Online:2017-10-28 Published:2017-10-31

摘要: 废弃的柚子皮中富含大量的木质素、纤维素、多糖及果胶等成分,因而具有与重金属发生作用的功能团,可作为重金属离子的吸附剂。研究以柚子皮粉和经过碱化改性、酯化改性、壳聚糖交联处理的柚子皮粉为吸附剂对铅离子(Pb2+)的吸附情况进行比较,选择出最佳改性处理方法;然后考察最佳改性后的吸附剂在不同的吸附条件下,即吸附时间、吸附温度、Pb2+的初始浓度、吸附时的pH 和吸附剂的用量对吸附效率的影响,探究出最佳的吸附剂使用条件;最后探究了吸附剂的吸附动力学特性。结果表明:碱化改性的柚子皮吸附剂在pH 为4 ~ 6、温度为45 ℃、吸附剂的投加量为10 g/L、吸附时间为60 min、Pb2+初始浓度约为140 mg/L 的条件下,对Pb2+的吸附效果最佳,吸附效率达到92%以上。吸附动力学方程为t / qt = 0. 207 3 + 0. 103 5 t 。

关键词: 铅离子, 柚子皮, 碱化改性, 重金属, 生物吸附

Abstract: The pomelo peel,which is rich in lignin,cellulose,polysaccharide and pectin,etc. ,has functional interactions with heavy metals,it can be used as adsorbent for heavy metal ions. In this study,the best modification processing method for pomelo peel powder was chosen through the comparison of adsorption behaviors to Pb(Ⅱ)ions with unmodified,alkalization modified,esterification modified and chitosan crosslinking treated pomelo peel powder. The optimal adsorption conditions of the modified adsorbent were explored in different adsorption conditions such as adsorption time,adsorption temperature,initial concentration of Pb(Ⅱ)ions,pH level and dosage of adsorbent. The adsorption kinetics characteristics of adsorbent were further studied. The results showed that the most suitable conditions for adsorbing Pb(Ⅱ)ions were alkalization modified pomelo peel powder with dosage of 10 g/L at pH 4-6,with absorbing time of 60 min and initial concentration of Pb(Ⅱ)ions as 140 mg/L. The adsorption rate reached more than 92%. The adsorption kinetics equation is:t / qt = 0. 207 3 + 0. 103 5 t .

Key words: Pb(Ⅱ)ions, pomelo peel, alkalization modification, heavy metal, biological adsorption

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