江汉大学学报(自然科学版) ›› 2016, Vol. 44 ›› Issue (6): 514-519.doi: 10.16389/j.cnki.cn42-1737/n.2016.06.006

• 化学与生物学 • 上一篇    下一篇

食品中有害无机元素镉的含量测定方法比较

郭艳华,吴旺喜,张玉敏,李艾华   

  1. 江汉大学 化学与环境工程学院,湖北 武汉 430056
  • 出版日期:2016-12-28 发布日期:2016-12-30
  • 作者简介:郭艳华(1960—),女,教授,研究方向:天然产物化学及光电功能材料。
  • 基金资助:
    武汉市科技局科技平台项目(2014022905011274)

Comparison of Determination Method of Cadmium Content of Harmful Inorganic Elements in Foods

GUO Yanhua,WU Wangxi,ZHANG Yumin,LI Aihua   

  1. School of Chemistry and Enviornmental Engineering,Jianghan University,Wuhan 430056,Hubei,China
  • Online:2016-12-28 Published:2016-12-30

摘要: 采用不同的消解方法和测定方法,测定食品中无机元素镉的含量并进行比较,同时利用统计方法进行数据处理,然后进行对比分析,从而得出测定食品中镉含量更适宜的消解与测定方法。结果表明:湿法消解用石墨炉原子吸收光谱法与湿法消解用火焰原子吸收光谱法测量的回收率相差不大,湿法消解用火焰原子吸收光谱法的标准偏差最小,其精密度最高。综合比较:采用湿法消解方法和火焰原子吸收光谱法对食品中镉元素进行测定更为合理。

关键词: 镉, 石墨炉原子吸收光谱法, 火焰原子吸收光谱法, 干法消解, 湿法消解

Abstract: With different digestion method and measuring method,the cadmium content of harmful inorganic elements in foods was determined and compared,meanwhile,the statistical methods for data processing were used, and then the data were analyzed, thus the more suitable digestion and determination methods were found. The results showed that wet digestion with graphite furnace atomic absorption spectrometry and the wet digestion with flame atomic absorption spectrometry were used to measure the recovery,the differences of recovery rates were small,the standard deviation of wet digestion with flame atomic absorption spectrometry was the smallest and the precision was the highest.Comprehensive comparison showed the determination of cadmium in foods with the wet digestion and flame atomic absorption spectrometry was most reasonable.

Key words: cadmium, graphite furnace atomic absorption spectrometry, flame atomic absorption spectrometry, dry digestion;wet digestion

中图分类号: