江汉大学学报(自然科学版) ›› 2022, Vol. 50 ›› Issue (3): 21-28.doi: 10.16389/j.cnki.cn42-1737/n.2022.03.003

• 化学工程 • 上一篇    下一篇

垃圾焚烧飞灰固化及重金属浸出特性研究

方文,吴振宇,肖翔,晋梅,李海峰*   

  1. 江汉大学 光电材料与技术学院,湖北 武汉 430056
  • 发布日期:2022-06-24
  • 通讯作者: 李海峰
  • 作者简介:方文(1983— ),女,实验师,硕士,研究方向:材料学。

Research on Solidification and Heavy Metal Leaching Characteristics of Waste Incineration Fly Ash

FANG Wen,WU Zhenyu,XIAO Xiang,JIN Mei,LI Haifeng*   

  1. School of Optoelectronic Materials & Technology,Jianghan University,Wuhan 430056,Hubei,China
  • Published:2022-06-24
  • Contact: LI Haifeng

摘要: 针对垃圾焚烧飞灰重金属浸出不利于飞灰的资源化利用及填埋的问题,使用乙烯副产物进行磺化反应合成固化剂,考察其与螯合剂的协同作用对飞灰固化特性的影响。同时,考察pH及温度等环境条件对飞灰中重金属浸出特性的影响。实验结果表明:固化剂BFS 的添加可以改善飞灰的固化特性,抑制铅、镉、锌及铬等重金属的浸出;飞灰的重金属残留率随固化剂BFS 添加剂量的增大而先增大后减小。同时,浸提液的pH 与温度对于飞灰中重金属的浸出具有重要的影响:铅、镉、锌及铬等重金属特性在不同的pH 条件下有所不同。浸提温度过高和过低都不利于飞灰中重金属的稳定,实验中抑制3 种重金属浸出的最佳温度为35 ℃。

关键词: 垃圾焚烧飞灰, 螯合剂, 固化剂, 重金属浸出特性

Abstract: Aiming at the problem that the leaching of heavy metals from waste incineration fly ash was not conducive to the resource utilization and landfilling of fly ash,the byproduct of ethylene was used to synthesize an organic curing agent(BFS)with sulfonation reaction,and the effect of its synergistic effect of BFS and the chelating agent on the curing characteristics of fly ash was investigated. Meantime, the effects of environmental conditions,such as pH and temperature,on the leaching characteristics of heavy metals in fly ash were investigated. The experimental results showed that the addition of the curing agent BFS could significantly improve the curing characteristics of fly ash and inhibit the leaching of heavy metals,such as zinc,cadmium,chromium,and lead. The residual rate of heavy metals in fly ash increased firstly and then decreased with the increase of the loading of the curing agent BFS. The pH and temperature of the extracted liquid had an essential effect on the leaching of heavy metals in fly ash:the leaching characteristics of heavy metals,such as zinc,cadmium,chromium,and lead,were different under different pH conditions. Too high or low extract liquid temperature was not conducive to the stability of heavy metals in fly ash. In the experiment,the best extract liquid temperature was 35 ℃.

Key words: waste incineration fly ash, chelating agent, curing agent, leaching characteristics of heavy metal

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