江汉大学学报(自然科学版) ›› 2019, Vol. 47 ›› Issue (4): 327-332.doi: 10.16389/j.cnki.cn42-1737/n.2019.04.006

• 化学 • 上一篇    下一篇

改性再生纤维素膜的制备及表征

胡思前,王刚,朱天容*   

  1. 光电化学材料与器件教育部重点实验室(江汉大学),湖北 武汉 430056
  • 出版日期:2019-08-28 发布日期:2019-07-10
  • 通讯作者: 朱天容
  • 作者简介:胡思前(1963—),男,教授,研究方向:功能材料。
  • 基金资助:
    江汉大学博士科研启动基金资助项目(2012021);光电化学与器件教育部重点实验室开放基金资助项目(JDGD-201609)

Preparation and Characterizations of Modified Regenerated Cellulose Membrane

HU Siqian,WANG Gang,ZHU Tianrong*   

  1. Key Laboratory of Optoelectronic Chemical Materials and Devices(Jianghan University),Ministry of Education,Wuhan 430056,Hubei,China
  • Online:2019-08-28 Published:2019-07-10
  • Contact: ZHU Tianrong

摘要: 为了获得改性再生纤维素膜并对改性再生纤维素膜的性能有所了解,以聚乙烯醇(PVA)1750±50、1799 和多壁碳纳米管(MWCNT)为材料分别对纤维素膜进行改性试验,通过差示扫描量热法和拉伸强度试验对改性膜进行了性能表征。结果表明:PVA1750±50、PVA1799、MWCNT 与再生纤维素有良好的兼容性;PVA1750±50 和PVA1799 均能提高改性膜的拉伸强度;当PVA1750±50 含量为1%时,改性膜热分解温度提高,热稳定性增强;改性膜的溶胀性较纯RC膜均有提高,吸水性能增强。

关键词: 改性膜, 再生纤维素膜, 聚乙烯醇(PVA), 多壁碳纳米管(MWCNT)

Abstract: To obtain modified regenerated cellulose membranes and understand its properties,the modification experiments were carried out with polyvinyl alcohol(PVA)1750±50,1799 and multiwalled carbon nanotubes(MWCNT)as materials,respectively. The features of the modified membranes were characterized by differential scanning calorimetry(DSC)and tensile strength tests. The results showed that PVA1750 ± 50, PVA1799, MWCNT had excellent compatibility with regenerated cellulose;both PVA1750 ± 50 and PVA1799 could improve the tensile strength of the modified membranes. When the content of PVA1750±50 was 1%,the thermal decomposition temperature and thermal stability of the modified membranes increased. The swelling capacity of the modified membranes was improved compared with that of pure RC membranes,and the water absorption performance was enhanced.

Key words: modified membrane, regenerated cellulose membrane, polyvinyl alcohol(PVA), multiwalled carbon nanotubes(MWCNT)

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