江汉大学学报(自然科学版) ›› 2024, Vol. 52 ›› Issue (5): 5-16.doi: 10.16389/j.cnki.cn42-1737/n.2024.05.001

• 光电化学材料与器件研究 • 上一篇    

MgCo2@O4Co(OH)2复合材料的制备及电化学性能研究

倪 航,胡潭伟,唐梦凡,丁 悦,田 玉*,朱小龙,郑 广   

  1. 江汉大学 光电化学材料与器件教育部重点实验室,湖北 武汉 430056
  • 发布日期:2024-10-24
  • 通讯作者: 田 玉
  • 作者简介:倪 航(1993— ),男,硕士生,研究方向:无机纳米材料超级电容器性能及器件。
  • 基金资助:
    江汉大学一流学科建设重大研究专项(2023XKZ007)

Preparation and Electrochemical Properties of MgCo2O4@Co(OH)2 Composite Material

NI Hang,HU Tanwei,TANG Mengfan,DING Yue,TIAN Yu,ZHU Xiaolong,ZHENG Guang   

  1. Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of Education,Jianghan University, Wuhan 430056,Hubei,China
  • Published:2024-10-24
  • Contact: TIAN Yu

摘要: 由于复合材料具有丰富的活性位点与良好的导电性能,已成为超级电容器电极材料的研 究热点之一。通过水热和电沉积法在泡沫镍上成功制备了 MgCo2O4@Co(OH)2 复合材料,采用 X 射线衍射(XRD)、扫描电镜(SEM)以及电化学工作站对产物进行了表征和电化学性能测试。 结果表明,该复合材料作为一种无粘结剂的超级电容器电极材料在电流密度为 1 mA/cm2下的比 电容高达 3 034. 75 F/g;在 14 mA/cm2 的电流密度下循环 1 000 圈后,比电容保持了 96%,展示出 MgCo2O4作为能量存储电极材料的巨大潜力。

关键词: 电沉积法, MgCo2O4@Co(OH)2复合材料, 比电容, 循环性能

Abstract: Composite materials have become one of the hot topics for supercapacitors′ electrode material because of their abundant active sites and excellent electroconductivity performance. MgCo2O4@Co(OH)2 composite material was successfully synthesized on Ni foam by hydrothermal and electrodeposition in this work. The product was characterized by X-ray diffraction(XRD)and scanning electron microscopy(SEM),and the electrochemical performance of the product was tested by the electrochemical workstation. The results showed that this MgCo2O4@Co(OH)2 composite material exhibited a maximum capacitance of 3 034. 75 F/g at a current density of 1 mA/cm2 when used as a binder-free electrode material for electrochemical capacitors. After 1 000 cycles at the current density of 14 mA/cm2,the specific capacitance was maintained at 96%,manifesting the great potential of MgCo2O4 as an excellent material for energy storage.

Key words: electrodeposition, MgCo2O4@Co(OH)2composite material;specific capacitance; cycle performance

中图分类号: