江汉大学学报(自然科学版) ›› 2023, Vol. 51 ›› Issue (4): 5-16.doi: 10.16389/j.cnki.cn42-1737/n.2023.04.001

• 光电化学材料与器件研究 • 上一篇    

化学气相沉积法制备硅碳复合负极材料的研究进展

付祥南1,徐远健1,柴敬超1,张玉敏1,汪海平1,郑云1,解明1,刘志宏1,言搏2,言伟雄*2   

  1. 1. 江汉大学 光电材料与技术学院,光电化学材料与器件教育部重点实验室,湖北 武汉 430056; 2. 株洲弗拉德科技有限公司,湖南 株洲 412000
  • 发布日期:2023-08-19
  • 通讯作者: 言伟雄
  • 作者简介:付祥南(1997— ),男,硕士生,研究方向:锂离子电池失效分析。
  • 基金资助:
    国家自然科学基金资助项目(51872127,22139001);湖北省重点研发计划项目(2020BAA030);江 汉大学研究生科研创新基金项目

Research Progress on Silicon-Carbon Composite Anode Materials Prepared by Chemical Vapor Deposition

FU Xiangnan,XU Yuanjian,CHAI Jingchao,ZHANG Yumin,WANG Haiping,ZHENG Yun,XIE Ming,LIU Zhihong,YAN Bo,YAN Weixiong   

  1. 1. School of Optoelectronic Materials & Technology,Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of Education,Jianghan University,Wuhan 430056,Hubei,China;2. Zhuzhou Fullad Technology Co. ,Ltd. ,Zhuzhou 412000,Hunan,China
  • Published:2023-08-19
  • Contact: YAN Weixiong

摘要: 目前,利用硅材料的高比容量和碳材料的稳定性制备硅碳复合负极材料是最有效的途径 之一。在众多硅碳复合负极材料制备工艺中,因化学气相沉积法(CVD)制备的硅碳复合负极具 有充放电效率高、循环稳定性好、对设备要求较低、适合工业化生产等优势,受到了广泛关注。综 述了 CVD 法制备硅碳复合负极材料的研究进展,从硅碳复合材料结构角度,如核壳结构、蛋黄壳 结构、多孔结构和嵌入式结构,对不同结构类型的硅碳复合负极材料结构设计及电池性能等方面 进行介绍,同时阐述了各自优势以及存在的问题。最后介绍了 CVD 法制备硅碳复合负极材料应 用进展,并对硅碳复合负极材料产业化进行了展望。

关键词: 化学气相沉积, 硅碳复合负极, 锂离子电池

Abstract: At present,it is one of the most effective ways to prepare silicon-carbon composite anode materials by compositing the silicon materials with high specific capacity and the carbon materials with stability. Among the many preparation processes of silicon-carbon composite anode materials,the silicon-carbon composite anode prepared by chemical vapor deposition(CVD) has the advantages of high charging/discharging efficiency,good cycle stability,facile process,and is suitable for mass production. This paper summarized the research progress of preparing silicon-carbon composite anode materials by chemical vapor deposition. From the perspective of silicon-carbon composites structure,such as coreshell structure, yolk-shell structure, porous structure, and embedded structure, the structural design and battery performance of different types of silicon-carbon composite anode materials were introduced, and their advantages and existing the problem were discussed. Finally,the application of silicon-carbon composite anode materials prepared by CVD was summarized,and we prospected the future of industrialization of silicon-carbon composite anode materials.

Key words: chemical vapor deposition, silicon-carbon composite anode, lithium-ion battery

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