江汉大学学报(自然科学版) ›› 2019, Vol. 47 ›› Issue (4): 339-344.doi: 10.16389/j.cnki.cn42-1737/n.2019.04.008

• 化学 • 上一篇    下一篇

LTCC 内电极导电银浆的共烧收缩率调节

宋斌1,王亚珍*2,黄月文1   

  1. 1. 中科院广州化学有限公司,广东 广州 510650;2. 江汉大学 化学与环境工程学院,湖北 武汉 430056
  • 出版日期:2019-08-28 发布日期:2019-07-10
  • 通讯作者: 王亚珍
  • 作者简介:宋斌(1989—),男,硕士,研究方向:电子材料与浆料、功能高分子材料。

Adjustment of Co-firing Shrinkage Rate of LTCC Internal Electrode Conductive Silver Paste

SONG Bin1,WANG Yazhen*2,HUANG Yuewen1   

  1. 1. Guangzhou Chemistry Co.,Ltd.,Chinese Academy of Sciences,Guangzhou 510650,Guangdong,China;2. School of Chemical and Environmental Engineering,Jianghan University,Wuhan 430056,Hubei,China
  • Online:2019-08-28 Published:2019-07-10
  • Contact: WANG Yazhen

摘要: LTCC 内电极银浆面临与生瓷带的共烧匹配问题,通过银粉粒径、级配和树脂的选型、含量的优化,减少共烧收缩率和生瓷带收缩率之间的差距。优化的条件为:银粉粒径分布D50为3. 9 μm,银粉级配mSIL31∶ mSIL32 = 1∶1,树脂选型为乙基纤维素(EC4、EC10)和丙烯酸树脂,有机载体中树脂含量为20%。在优化的条件下基体共烧平整,且银层展现高导电性,电阻率为0. 048 Ω·mm2/m。

关键词: LTCC, 内电极, 银浆, 共烧

Abstract: LTCC internal electrode silver paste was faced the co-firing match problem with green tape. The gap of shrinkage rate between co-firing and green tape was reduced by adjusting the particle size and grade of silver powders,and by optimizing the type and content of resins. The optimum conditions were as below:silver powder particle size distribution D50 was 3. 9 μm,silver powder grade was mSIL31∶mSIL32 = 1∶1,resin type was ethyl cellulose(EC4,EC10)and acrylic resin,content of the resin in the organic carrier was 20% 。Under the optimized conditions,the substrate co-fires flatted,and the silver layer showed high conductivity,the electrical resistivity was 0. 048 Ω·mm2/m.

Key words: low-temperature co-firing ceramic(LTCC), internal electrode, silver paste;co-firing

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