江汉大学学报(自然科学版) ›› 2012, Vol. 40 ›› Issue (1): 47-49.

• 化学 • 上一篇    下一篇

TiO2/甲壳素光催化降解甲基橙的性能

彭湘红,程德翔,石红   

  1. 江汉大学化学与环境工程学院,湖北武汉430056
  • 收稿日期:2011-07-05 出版日期:2012-02-20 发布日期:2013-11-07
  • 作者简介:彭湘红单位1966—),女,教授,博士,研究方向:天然高分子材料的应用。
  • 基金资助:
    武汉市科委项目单位0751699478-016

TiO2 /Chitin Composite for Photocatalytic Degradation of Methyl Orange

PENG Xiang-hong,CHENG De-xiang,SHI Hong   

  1. School of Chemistry and Environmental Engineering,Jianghan University,Wuhan 430056,Hubei,China
  • Received:2011-07-05 Online:2012-02-20 Published:2013-11-07

摘要: 以钛酸四丁酯为钛原料,通过升高温度使尿素逐渐分解的方法制备胶体TiO2,将胶体TiO2固定到甲壳素上得到TiO2/甲壳素。以甲基橙水溶液为光催化降解模型,用分光光度计法测定TiO2/甲壳素的光催化性能。结果表明在100min的紫外光下,TiO2/甲壳素对甲基橙的催化降解率达到75.6%;经150min太阳光照射,TiO2/甲壳素对甲基橙的降解率达到52.3%。TiO2/甲壳素对甲基橙10次的降解率在45.1%到73.9%之间。TiO2/甲壳素的红外光谱图有O-Ti-O键的特征吸收峰952.8cm-1。本工作制备的TiO2/甲壳素具有良好的光催化降解甲基橙的能力。

关键词: 二氧化钛, 甲壳素, 甲基橙, 降解, 太阳光

Abstract: Used tetrabutyl titanate as material, increased the temperature to gradually degrade the ureophil to prepare the colloid TiO2, fixed the colloid TiO2 on chitin and obtained TiO2/chitin. Methyl orange solution was used as model, the photocatalytic degradation ratio with TiO2/chitin was investigated by spectrophotometer method. The results revealed that the TiO2/chitin was an efficient photocatalyst for the degradation of methyl orange, and 75.6% of the methyl orange was degraded after 100 min using UV light,and 52.3% of the methyl orange was degraded under the sunlight after 150 min, respectively. The TiO2/chitin could degradate methyl orange for 10 times, and the degradation ratio was from 45.1% to 73.9%. There existed the peak belonging to the O-Ti-O band absorption at 952.8 cm-1. The TiO2/chitin has efficient ability for degradation of methyl orange.

Key words: TiO2, chitin, methyl orange, degradation, sunlight

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