江汉大学学报(自然科学版) ›› 2020, Vol. 48 ›› Issue (6): 5-12.doi: 10.16389/j.cnki.cn42-1737/n.2020.06.001

• 光电化学材料与器件研究 • 上一篇    下一篇

以碳布为基底制备NaV6O15纳米棒及其电化学性能研究

刘万能,倪航,毛志鹏,田玉,朱小龙*,郑广   

  1. 江汉大学 光电化学材料与器件教育部重点实验室,化学与环境工程学院,湖北 武汉 430056
  • 出版日期:2020-12-28 发布日期:2020-12-18
  • 作者简介:刘万能(1995— ),男,硕士生,研究方向:无机纳米材料超级电容器性能及器件。
  • 基金资助:
    ZHU Xiaolong

Preparation of NaV6O15 Nanorods on Carbon Cloth and Their Electrochemical Properties

LIU Wanneng,NI Hang,MAO Zhipeng,TIAN Yu,ZHU Xiaolong* ,ZHENG Guang   

  1. Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of Education,School of Chemical and Environmental Engineering,Jianghan University,Wuhan 430056,Hubei,China
  • Online:2020-12-28 Published:2020-12-18
  • Contact: 朱小龙
  • Supported by:
    国家自然科学基金资助项目(61941502);湖北省自然科学基金资助项目(2019CFB205);湖北省教育厅科学研究计划指导性项目(B2019242);武汉教育局市属高校产学研项目(CXY201803)

摘要: NaV6O15是一种性能优越的纳米材料,在超级电容器领域具有很大的应用前景。为了获得性能更加优良的电极体系,以碳布为基底,通过水热法在碳布上合成NaV6O15前躯体。将该碳布进行退 火处理,使碳布上的NaV6O15前躯体通过晶格重构转化为直径30 ~ 100 nm 不等的NaV6O15纳米棒晶体并牢固地“ 长”在碳布的每一束纤维丝上。使用X 射线衍射仪、扫描电子显微镜和电化学工作站对该电极材料进行物相、形貌和电化学分析,结果表明,在电流密度为0. 5 A/g 时,比电容为735. 3 F/g,经3 000 次循环后,其电容保持率为85%,此外该电极材料还具有良好的倍率性能、较高的能量密度和极低的内阻,其电化学性能较涂敷电极有较大提升。

关键词: NaV6O15纳米棒, 比电容, 循环性能, 碳布

Abstract: NaV6O15 is a kind of nanomaterial with superior performance and has great application prospects in the field of supercapacitors. In order to obtain an electrode system with better performance,NaV6O15 was synthesized on carbon cloth as a precursor using the hydrothermal method in this paper. The carbon cloth was annealed,and the NaV6O15 precursor on the carbon cloth was transformed into crystals of NaV6O15 nanorod with diameters ranging from 30 nm to 100 nm through lattice reconstruction,which firmly grew on each bunch of fiber filaments of the carbon cloth. X-ray diffractometer,scanning electron microscope and electrochemical workstation were used for phase、morphology and electrochemical analysis of the electrode material. The results showed that the specific capacitance was 735. 3 F/g at the current density of 0. 5 A/g,and after 3 000 cycles,its capacitance retention rate was 85%. In addition,the electrode material also had good rate performance,higher energy density and extremely low internal resistance. Its electrochemical performance is greatly improved compared to coated electrodes.

Key words: NaV6O15 nanorods, specific capacitance, cycling performance, carbon cloth

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